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Kinetics and Mechanism of Electron-Transfer Reactions: Oxidation of Butanone and Cyclohexanone by Thallium (III) in Acid Perchlorate Medium- An Appraisal of Keto Form Reactivity
Shalini Hemkar,
Riya Sailani,
Chandra Lata Khandelwal,
Prem Dutt Sharma
Issue:
Volume 2, Issue 5, October 2013
Pages:
73-79
Received:
8 August 2013
Published:
10 September 2013
Abstract: The kinetics of oxidation of ketones by thallium (III) has been studied in acid perchlorate medium. The reaction does not indicate enolization to be the rate controlling step in the reaction mechanism. The kinetic rate law (1) has been observed. -d[TlIII] / dt= k1Kh [Tl(III)Ketone] / ([H+] + Kh) Where Kh is the hydrolysis constant of the oxidant. A plausible reaction mechanism is suggested conforming to the rate law (1). Activation parameters were evaluated.
Abstract: The kinetics of oxidation of ketones by thallium (III) has been studied in acid perchlorate medium. The reaction does not indicate enolization to be the rate controlling step in the reaction mechanism. The kinetic rate law (1) has been observed. -d[TlIII] / dt= k1Kh [Tl(III)Ketone] / ([H+] + Kh) Where Kh is the hydrolysis constant of the oxidant. A...
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Some Specific Plausible Theoretical Aspects to Justify and Support the Existence of Thought-Carrying Particle, Thought Retaining Particle and Thought Force
Issue:
Volume 2, Issue 5, October 2013
Pages:
80-93
Received:
10 October 2013
Published:
20 November 2013
Abstract: A single field emerged at the origin of the universe, already containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. Scientists have arrived at a simple but decisive conclusion that consciousness is very much a part of the universe, like other objects. Our consciousness model involving thought-carrying particle (TCP), thought retaining particle (TRP) and thought force (TF) signifies the existence of universal consciousness that exists along with the universe. This universal consciousness is a functional state of the universal mind (UM). This UM is evolved at the Big Bang from void. The UM is constituted by these TCP and TRP in the inherent presence of thought force (TF). Thought force (TF) is an expression of universal consciousness. The Thought force (TF) being the primordial quantum field functions as the original super-force. TF being the original super-force functions as the origin of all the fundamental fields. TCP is the carrier of thought force (TF) that, in turn, appears to be the origin of all the fields. The quantized energy of TCP is responsible to cause the universal consciousness as well as the cosmic microwave background radiation temperature. The individual consciousness owes its origin to the universal consciousness created by the same . The same is the energy responsible for generating thought force (TF). TF being an expression of the universal consciousness is applicable to any inanimate object as well as to any biological system (having thinking ability). The TF exerts its functions both in vitro and in vivo.We showed the existence of thought force in microcosm [TF (micro)] and thought force in macrocosm [TF (macro)]. This TF (micro) is theoretically found to be stronger than the strong nuclear force. TF (macro) is theoretically found to be weaker even than the gravitational force. Any matter as well as any individual mind is constituted by these TCP and TRP that are originated from same Void. Some plausible theoretical scientific aspects have been specified here to justify and support the existence of TCP, TRP and thought force (TF)) along with the TF (micro) and TF (macro). These TCP, TRP and thought force (TF) can provide guidelines to form a possible gross bridge between mind and matter, present physics and cognitive science, psychology and natural sciences, classical physics and quantum physics.
Abstract: A single field emerged at the origin of the universe, already containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. Scientists have arrived at a simple but decisive conclusion that c...
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Existence of Thought Force and Its Characteristics
Issue:
Volume 2, Issue 5, October 2013
Pages:
94-104
Received:
29 September 2013
Published:
20 November 2013
Abstract: A single field emerged at the origin of the universe containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. As per Penrose, consciousness is a part of the universe. Our consciousness model involving thought-carrying particle (TCP), thought retaining particle (TRP) and thought force (TF) signifies the existence of universal consciousness that exists along with the universe. This universal consciousness is a functional state of the universal mind. This universal mind (UM) is evolved at the Big Bang from Void. The UM is constituted by these TCP and TRP in the inherent presence of thought force (TF). Thought force (TF) is an expression of universal consciousness. This TF being the primordial quantum field functions as the original super-force. TF being the original super-force functions as the origin of all the fundamental fields. TCP is the carrier of thought force (TF) that, in turn, appears to be the origin of all the fields. The quantized energy (εT) of TCP is responsible to cause the cosmic microwave background radiation temperature as well as the universal consciousness. The individual consciousness owes its origin to the universal consciousness. The same is the energy responsible for generating thought force (TF). This TF being applicable to any inanimate object as well as to any biological system (having thinking ability) exerts its function both in vitro and in vivo. Existence of thought force and its characteristics are expressed here.
Abstract: A single field emerged at the origin of the universe containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. As per Penrose, consciousness is a part of the universe. Our consciousness ...
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Possible Bridge between the Mind and Matter: The Physical World is nothing but a Projection of the Mind Consisting of TCP and TRP that, in Turn, are the Ultimate Constituents of any Matter also
Issue:
Volume 2, Issue 5, October 2013
Pages:
105-116
Received:
31 October 2013
Published:
20 November 2013
Abstract: A single field emerged at the origin of the universe, already containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. Scientists have arrived at a simple but decisive conclusion that consciousness is very much a part of the universe, like other objects. Our consciousness model involving thought-carrying particle (TCP), thought retaining particle (TRP) and thought force (TF) signifies the existence of universal consciousness that exists along with the universe. This universal consciousness is a functional state of the universal mind (UM). This UM is evolved at the Big Bang from void. The UM is constituted by these TCP and TRP in the inherent presence of thought force (TF). Thought force (TF) is an expression of universal consciousness. The Thought force (TF) being the primordial quantum field functions as the original super-force. TF being the original super-force functions as the origin of all the fundamental fields. TCP is the carrier of thought force (TF) that, in turn, appears to be the origin of all the fields. The quantized energy (εT) of TCP is responsible to cause the universal consciousness as well as the cosmic microwave background radiation temperature. The individual consciousness owes its origin to the universal consciousness created by the sameεT. The sameεT is the energy responsible for generating thought force (TF). TF being an expression of the universal consciousness is applicable to any inanimate object as well as to any biological system (having thinking ability). The TF exerts its functions both in vitro and in vivo. Any matter as well as any individual mind is constituted by these TCP and TRP in the inherent presence of thought force (TF) in vitro and thought force (TF) in vivo and these TCP and TRP are originated from the same Void. These TCP, TRP and the thought force (TF) in vitro and thought force (TF) in vivo play significant roles in understanding matter, mind and consciousness and in the formation of a possible bridge between the mind and matter.
Abstract: A single field emerged at the origin of the universe, already containing within itself the blueprint of the physical universe. The primordial single field triggered the onset of the universe. Most physicists believe that a single super-force dominated the first instants of creation. Scientists have arrived at a simple but decisive conclusion that c...
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