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Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten

Received: 9 December 2020     Accepted: 24 December 2020     Published: 12 January 2021
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Abstract

The whole world is interested in the metal industry and its permanent development. One of these metals is carbon steel. Therefore, scientists tend to improve the properties of this metal, in this research we have improved the properties of carbon steel through electroless plating process of Ni-P and Ni-W-P alloys. In different industries, electroless nickel-phosphorus Ni-P and nickel-tungsten-phosphorus Ni-W-P deposits have been commonly used as engineering safety coatings. In our research, Ni-P and Ni-W-P were deposited on low carbon steel by using acid bath. To study the improvement of the properties of the coats, microstructure analysis investigated by thin film (XRD), coat’s morphology by electron microscope scan (SEM), analyzing the coat by X-ray dispersive energy (EDX) and protection of corrosion of the coats were determined by potentiodynamic polarization measurements in artificial sea water (3.5% NaCl solution). The results indicated that the phases formed from the electroless coating give excellent corrosion resistance of low carbon steel and also indicated that the alloy formed in the presence of tungsten through the electroless bath give higher corrosion protection than that formed without it. As the concentration of tungstate increase in the bath, coat has higher corrosion protection i.e. Ni-W-P III>Ni-W-P II >Ni-W-P I>Ni-P.

Published in American Journal of Physical Chemistry (Volume 10, Issue 1)
DOI 10.11648/j.ajpc.20211001.11
Page(s) 1-5
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Electroless, Ni – P, Ni – W – P, Low Carbon Steel

References
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  • APA Style

    Samar Refaat Gooda, Omyma Ramadan Mohammed Khalifa, Aisha Kassab Abd El-Aziz, Amany Hassan Marii. (2021). Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten. American Journal of Physical Chemistry, 10(1), 1-5. https://doi.org/10.11648/j.ajpc.20211001.11

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    ACS Style

    Samar Refaat Gooda; Omyma Ramadan Mohammed Khalifa; Aisha Kassab Abd El-Aziz; Amany Hassan Marii. Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten. Am. J. Phys. Chem. 2021, 10(1), 1-5. doi: 10.11648/j.ajpc.20211001.11

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    AMA Style

    Samar Refaat Gooda, Omyma Ramadan Mohammed Khalifa, Aisha Kassab Abd El-Aziz, Amany Hassan Marii. Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten. Am J Phys Chem. 2021;10(1):1-5. doi: 10.11648/j.ajpc.20211001.11

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  • @article{10.11648/j.ajpc.20211001.11,
      author = {Samar Refaat Gooda and Omyma Ramadan Mohammed Khalifa and Aisha Kassab Abd El-Aziz and Amany Hassan Marii},
      title = {Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten},
      journal = {American Journal of Physical Chemistry},
      volume = {10},
      number = {1},
      pages = {1-5},
      doi = {10.11648/j.ajpc.20211001.11},
      url = {https://doi.org/10.11648/j.ajpc.20211001.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20211001.11},
      abstract = {The whole world is interested in the metal industry and its permanent development. One of these metals is carbon steel. Therefore, scientists tend to improve the properties of this metal, in this research we have improved the properties of carbon steel through electroless plating process of Ni-P and Ni-W-P alloys. In different industries, electroless nickel-phosphorus Ni-P and nickel-tungsten-phosphorus Ni-W-P deposits have been commonly used as engineering safety coatings. In our research, Ni-P and Ni-W-P were deposited on low carbon steel by using acid bath. To study the improvement of the properties of the coats, microstructure analysis investigated by thin film (XRD), coat’s morphology by electron microscope scan (SEM), analyzing the coat by X-ray dispersive energy (EDX) and protection of corrosion of the coats were determined by potentiodynamic polarization measurements in artificial sea water (3.5% NaCl solution). The results indicated that the phases formed from the electroless coating give excellent corrosion resistance of low carbon steel and also indicated that the alloy formed in the presence of tungsten through the electroless bath give higher corrosion protection than that formed without it. As the concentration of tungstate increase in the bath, coat has higher corrosion protection i.e. Ni-W-P III>Ni-W-P II >Ni-W-P I>Ni-P.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten
    AU  - Samar Refaat Gooda
    AU  - Omyma Ramadan Mohammed Khalifa
    AU  - Aisha Kassab Abd El-Aziz
    AU  - Amany Hassan Marii
    Y1  - 2021/01/12
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajpc.20211001.11
    DO  - 10.11648/j.ajpc.20211001.11
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 1
    EP  - 5
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20211001.11
    AB  - The whole world is interested in the metal industry and its permanent development. One of these metals is carbon steel. Therefore, scientists tend to improve the properties of this metal, in this research we have improved the properties of carbon steel through electroless plating process of Ni-P and Ni-W-P alloys. In different industries, electroless nickel-phosphorus Ni-P and nickel-tungsten-phosphorus Ni-W-P deposits have been commonly used as engineering safety coatings. In our research, Ni-P and Ni-W-P were deposited on low carbon steel by using acid bath. To study the improvement of the properties of the coats, microstructure analysis investigated by thin film (XRD), coat’s morphology by electron microscope scan (SEM), analyzing the coat by X-ray dispersive energy (EDX) and protection of corrosion of the coats were determined by potentiodynamic polarization measurements in artificial sea water (3.5% NaCl solution). The results indicated that the phases formed from the electroless coating give excellent corrosion resistance of low carbon steel and also indicated that the alloy formed in the presence of tungsten through the electroless bath give higher corrosion protection than that formed without it. As the concentration of tungstate increase in the bath, coat has higher corrosion protection i.e. Ni-W-P III>Ni-W-P II >Ni-W-P I>Ni-P.
    VL  - 10
    IS  - 1
    ER  - 

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Author Information
  • Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt

  • Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt

  • Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt

  • Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt

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